Thermodynamic equilibrium is an axiomatic concept of thermodynamics. It is an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls. In thermodynamic equilibrium there are no net macroscopic flows of matter or of energy, within a system or between systems. In a system that is in its own state of internal thermodynamic equilibrium, no macroscopic change occurs. Systems in mutual thermodynamic equilibrium are simultaneously in mutual thermal, mechanical, chemical, and radiative equilibria. Systems can be in one kind of mutual equilibrium, while not in others. In thermodynamic equilibrium, all kinds of equilibrium hold at once and indefinitely, until disturbed by a thermodynamic operation. In a macroscopic equilibrium, perfectly or almost perfectly balanced microscopic exchanges occur; this is the physical explanation of the notion of macroscopic equilibrium. A thermodynamic system in a state of internal thermodynamic equilibrium has a spatially uniform temperature. Its intensive properties, other than temperature, may be driven to spatial inhomogeneity by an unchanging long-range force field imposed on it by its surroundings. In systems that are at a state of non-equilibrium there are, by contrast, net flows of matter or energy. If such changes can be triggered to occur in a system in which they are not already occurring, the system is said to be in a meta-stable equilibrium. Though not a widely named "law," it is an axiom of thermodynamics that there exist states of thermodynamic equilibrium. The second law of thermodynamics states that when an isolated body of material starts from an equilibrium state, in which, portions of it are held at different states by more or less permeable or impermeable partitions, and a thermodynamic operation removes or makes the partitions more permeable, then it spontaneously reaches its own, new state of internal thermodynamic equilibrium, and this is accompanied by an increase in the sum of the entropies of the portions. (Wikipedia).
How an Equilibrium Constant varies with Temperature - Thermodynamics - Physical Chemistry
Deriving a quantitative relationship to show how an equilibrium constant varies with temperature and so showing were Le Chatelier's Principle comes from in this context. Along the way, the Gibbs-Helmholtz van't Hoff equations are derived and used. My video for deriving the thermodynamics
From playlist Introductory Thermodynamics
Thermodynamic System | Open, Closed, Adiabatic, Isolated | Statistical Mechanics
In this video, we will define a thermodynamic system, in particular what kinds of thermodynamic systems there are and how they can interact with their surroundings. References: [1] Ansermet, Brechet, "Principles of Thermodynamics", Cambridge University Press (2019). Follow us on Insta
From playlist Thermodynamics, Statistical Mechanics
Equilibrium occurs when the overall state of a system is constant. Equilibrium can be static (nothing in the system is changing), or dynamic (little parts of the system are changing, but overall the state isn't changing). In my video, I'll demonstrate systems in both types of equilibrium,
From playlist Physics
Physics - Thermodynamics 2: Ch 32.1 Def. and Terms (7 of 23) Visiual Rep. of Equilibrium State
Visit http://ilectureonline.com for more math and science lectures! In this video I will give and explain a visual representation of equilibrium state and equation of state. Next video in this series can be seen at: https://youtu.be/UHjnWqmt_OA
From playlist PHYSICS 32.1 THERMODYNAMICS 2 BASIC TERMS
Physics - Thermodynamics 2: Ch 32.1 Def. and Terms (1 of 25) Basic Terms
Visit http://ilectureonline.com for more math and science lectures! In this video I will give and explain the basic terms of thermodynamic heat flow, thermodynamic equilibrium, temperature, system, open system, closed system, and isolated system. Next video in this series can be seen at:
From playlist PHYSICS 32.1 THERMODYNAMICS 2 BASIC TERMS
Physics - Thermodynamics: (2 of 14) What is the Second Law of Thermodynamics? (No 100% Efficiency)
Visit http://ilectureonline.com for more math and science lectures! In this video I will explain the 2nd Law of Thermodynamics (no 100% efficiency).
From playlist PHYSICS - THERMODYNAMICS
Thermodynamics 3a - Energy and the First Law I
Having developed our ideal-gas model in the previous video, we now use that model to understanding the principle and application of the First Law of Thermodynamics. Note on the definition of a "closed system." I am using the term "closed system" in the sense of the following definition fr
From playlist Thermodynamics
Teach Astronomy - Thermal Equilibrium
http://www.teachastronomy.com/ Thermal equilibrium is an important physical principle. When two substances have unequal temperatures, thermal equilibrium means that they will tend to evolve to a situation of equal temperature. At a microscopic level we know that temperature denotes the in
From playlist 04. Chemistry and Physics
Thermodynamics 4a - Entropy and the Second Law I
The Second Law of Thermodynamics is one of the most important laws in all of physics. But it is also one of the more difficult to understand. Central to it are the concepts of reversibility and entropy. Note on the definition of a "closed system." I am using the term "closed system" in th
From playlist Thermodynamics
Jakob Yngvason - Understanding Entropywithout Probability
Jakob Yngvason (University of Vienna) Understanding Entropy without Probability. In 1856, Rudolf Clausius coined the word entropy as a suitable name for what he had been calling the "transformational content of a body". The new word made it possible to state the second law of thermodynam
From playlist Large-scale limits of interacting particle systems
On the existence of thermodynamic potentials for quantum systems... by Takahiro Sagawa
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From playlist Classical and Quantum Transport Processes : Current State and Future Directions (ONLINE)2022
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Engineering MAE 91. Intro to Thermodynamics. Lecture 02.
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From playlist Engineering MAE 91. Intro to Thermodynamics
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From playlist Chemistry 131C: Thermodynamics and Chemical Dynamics
Zeroth law of thermodynamics | Chemical Processes | MCAT | Khan Academy
Visit us (http://www.khanacademy.org/science/healthcare-and-medicine) for health and medicine content or (http://www.khanacademy.org/test-prep/mcat) for MCAT related content. These videos do not provide medical advice and are for informational purposes only. The videos are not intended to
From playlist Chemical processes | MCAT | Khan Academy
Lec 1 | MIT 5.60 Thermodynamics & Kinetics, Spring 2008
Lecture 1: State of a system, 0th law, equation of state. View the complete course at: http://ocw.mit.edu/5-60S08 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu
From playlist MIT 5.60 Thermodynamics & Kinetics, Spring 2008
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From playlist T1-2015 : Disordered systems, random spatial processes and some applications
Physics - Thermodynamics: Radiation: Heat Transfer (8 of 11) Earth's Equilibrium Temperature
Visit http://ilectureonline.com for more math and science lectures! In this video I will show you how to calculate the Earth's equilibrium temperature.
From playlist PHYSICS - THERMODYNAMICS