Triphenyl phosphite ozonide (TPPO) is a chemical compound with the formula PO3(C6H5O)3 that is used to generate singlet oxygen. When TPPO is mixed with amines, the ozonide breaks down into singlet oxygen and leaves behind triphenyl phosphite. Pyridine is the only known amine that can effectively cause the break down of TPPO while not quenching any of the produced oxygen. (Wikipedia).
Making Triphenylarsine with Arsenic Metal
Support my channel with patreon: https://www.patreon.com/chemiolis In this video I am having my first attempt at organoarsenic chemistry. I bought an ampoule of arsenic metal which I chlorinated to arsenic(III)chloride using chlorine produced from pool chlorine tablets. I then used this t
From playlist Heavy Metal Chemistry
Make p-Chlorophenyl Acetonitrile - Step 4 in Pyrimethamine Synthesis
In this video we make p-chlorophenyl acetonitrile from the p-chlorobenzyl chloride and the sodium cyanide in a previous video. ( Complete pyrimethamine playlist so far: https://www.youtube.com/playlist?list=PLU79801KtVAU1XsTwHaKkqQoBgz_VYmPS ) Fortunately this is a very mild process and
From playlist Pyrimethamine
Hexamine is a solid fuel with a high energy density, and we make a salt with it using perchloric acid, a very good pyrotechnic oxidiser. I also try to be funny at the end. At the time, I remember it being actually funny to me, but now it's really quite hard to watch. Oh well, progress I g
From playlist Older Videos
Chem 201. Organic Reaction Mechanisms I. Lecture 20. Phosphorus Chemistry
UCI Chem 201 Organic Reaction Mechanisms I (Fall 2012) Lec 20. Organic Reaction Mechanism -- Phosphorus Chemistry View the complete course: http://ocw.uci.edu/courses/chem_201_organic_reactions_mechanisms_i.html Instructor: David Van Vranken, Ph.D. License: Creative Commons BY-NC-SA Terms
From playlist Chem 201: Organic Reaction Mechanisms I
27. Triphenylmethyl and an Introduction to Carbonyl Chemistry
Freshman Organic Chemistry II (CHEM 125B) Painstaking studies of his "hexaphenylethane" and its reactivity convinced Gomberg that he had prepared the first trivalent carbon compound, triphenylmethyl radical, the discovery of which marked the emergence of fundamental organic chemistry in
From playlist Freshman Organic Chemistry II with Michael McBride
Making Cyrene: the Next Common Solvent?
Support my channel with patreon: https://www.patreon.com/chemiolis Levoglucosenone synthesis: http://www.orgsyn.org/demo.aspx?prep=v97p0038 Hydrogenation of levoglucosenone: https://sci-hub.se/https://pubs.acs.org/doi/10.1021/acs.joc.6b02129 and https://sci-hub.se/https://doi.org/10.1
From playlist Chemistry with Natural Materials
Chem 125. Advanced Organic Chemistry. 20. Enamines, the Wittig Reaction, and Cyclopropanation.
UCI Chem 125 Advanced Organic Chemistry (Spring 2016) Lec 20. Enamines, the Wittig Reaction, and Cyclopropanation. View the complete course: http://ocw.uci.edu/courses/chem_125_advanced_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of U
From playlist Chem125: Advanced Organic Chemistry
REUPLOAD - Make 2-(p-chlorophenyl)-3-oxopentanenitrile - Step 5 in Pyrimethamine Synthesis
In this video we make 2-(p-chlorophenyl)-3-oxopentanitrile which is step 5 in our synthesis of Pyrimethamine Related videos: Drying alcohol: https://www.youtube.com/watch?v=NMfs3e9OdZQ Making sodium metal with domestically available chemicals: https://www.youtube.com/watch?v=jCrFFVVcPU
From playlist Pyrimethamine
Staudinger Reactions - Bioothogonal before Click Chemistry
The original bioorthogonal chemistry using azides and their reaction phosphines to form aza-ylids, which can do bioconjugation reactions and other useful transformations in organic synthesis. The aza-ylid (aminophosphorane) generated can react directly with water in a hydrolysis reaction
From playlist Organic Chemistry Mechanisms
Organic Chemistry 51C. Lecture 05. Aldehydes and Ketones: Reactions. (Nowick)
UCI Chem 51C Organic Chemistry (Spring 2012) Lec 05. Organic Chemistry -- Aldehydes and Ketones: Reactions -- View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html Instructor: James S. Nowick, Ph.D. License: Creative Commons BY-NC-SA Terms of Use: http://ocw
From playlist Chemistry 51C: Organic Chemistry (Nowick)
OZONIDES! Potassium and Cesium Ozonides. KO3, CsO3
Ozonides filmed with top-notch depth of field! Brought to you by my new professional lighting equipment that I bought thanks to your support! ____________________________ Support my channel! https://www.patreon.com/ChemicalForce PayPal: reactionsoup@gmail.com (Shcherba) Skrill: chemical
From playlist Oxidizers!
I poured liquid ammonia in LIQUID OZONE! NH4O3
In this video I mix dry liquid ammonia and almost-pure liquid ozone, that leads to the formation of unstable ammonium ozonide NH4O3! ____________________________ Support my channel! https://www.patreon.com/ChemicalForce PayPal: reactionsoup@gmail.com (Shcherba) ____________________________
From playlist Oxidizers!
Acylation of benzene || 3d Video Animation || Education
Acylation of benzene || 3d Video Animtaion || Education the mechanism for the c acyation of benzene involving an electrophilic substitution reaction between benzene and ethanoyl chloride in the presence of an aluminium chloride catalyst. The Friedel–Crafts acylation was first discovered i
From playlist Chemistry Topics
How to Memorize The Polyatomic Ions - Formulas, Charges, Naming - Chemistry
This chemistry video tutorial explains how to memorize the polyatomic ions. It provides the name of the common polyatomic ions, the charges and their respective formulas as well. Common polyatomic ions include sulfate, nitrate, acetate, ammonium, hydroxide, sulfite, cyanide, phosphate, d
From playlist New AP & General Chemistry Video Playlist
Chemistry 202. Organic Reaction Mechanisms II. Lecture 06. The Organic Chemistry of Phosphorus
UCI Chem 202 Organic Reaction Mechanisms II (Winter 2014) Lec 06. Organic Reaction Mechanism -- The Organic Chemistry of Phosphorus View the complete course: http://ocw.uci.edu/courses/chem_202_organic_reaction_mechanisms_ii.html Instructor: David Van Vranken, Ph.D. License: Creative Comm
From playlist Chemistry 202. Organic Reaction Mechanisms II
HSC Chemistry Industrial Chemistry Saponification
From playlist HSC Chemistry - Industrial Chemistry
Oxidative Cleavage of Alkenes & Alkynes - KMnO4 & Ozonolysis (IOC 27)
In this episode, I discuss the oxidative cleavage of alkenes and alkynes, using KMnO4 and ozone. Here is the video from ChemicalForce featuring liquid ozone: https://www.youtube.com/watch?v=vttsvMKQ1Yw *WARNING* ozone is very toxic, and ozonides can be explosive! Great care should be tak
From playlist Organic Chemistry Lectures
In this video, I discuss a retracted paper from Green Chemistry, where the authors use "magnetized water" for aromatic C-N bond formation. https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ --------------------------------------------------------------
From playlist Toxic
Video of ChemicalForce: https://youtu.be/WhcfBLop5gM Do you have any questions or suggestions? I would like to hear them in the comments! If you want, you can join my patreon to help me working on my projects. All posts will be public, so you can participate without paying. https://www.p
From playlist Cesium Reactions (Ozonide, Superoxide, Auride)
Total Synthesis of ent-Plagiochianin B
An organic chemistry minilecture on the Total Synthesis of ent-Plagiochianin B by Richard K. Jackson III and John L. Wood*. It features a creative azatriene electrocyclization pyridine synthesis, an exo-alkene selective palladium catalysed oxidation and an endo-alkene selective iron catal
From playlist Total Synthesis