Oxycations

Pervanadyl

Pervanadyl (VO+2) is a pale yellow oxycation of vanadium(V). It is the predominant vanadium(V) species in acidic solutions with pH between 0 and 2, and its salts are formed by protonation of vanadium(V) oxide in such solutions: V2O5 + 2 H+ → 2 VO+2 + H2O (K = 3.42×10−2) The ion can form a complex with a single aminopolycarboxylate ligand, or with tridentate Schiff base ligands. The VO+2/VO2+ redox couple is used at the cathode of the vanadium redox battery. The standard reduction potential of this couple is +1.00 V. (Wikipedia).

Pervanadyl
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