Octafluorocubane
Octafluorocubane or perfluorocubane is an organofluorine compound with the formula C8F8, consisting of eight carbon atoms joined into a cube, with a fluorine on each corner. It is a colorless sublimable solid. It has been of longstanding theoretical interest, but was not synthesised until 2022, when it was prepared in several steps from a cubane carboxylic ester beginning with its heptafluorination. According to X-ray crystallography, the C-C distances (1.572 Å) in octafluorocubane are identical in length to those in the parent cubane. Octafluorocubane has attracted interest from theorists because of its unusual electronic structure, which is indicated by its susceptibility to undergo reduction to a detectable anion C8F−8, with the free electron trapped in the inside of the cube. (Wikipedia).
